Low temperature catalytic ignition of hydrogen and oxygen

Catalyst composed of 32 percent iridium metal supported on granular alumina is most active and most stable of platinum metal catalysts. Catalyst consistently induces reactions at temperatures as low as 78 K

Development of Hydrogen-Oxygen Catalysts Final Report

Catalysts of improved activity and thermal stability for low temperature ignition of oxygen- hydrogen mixtur

Growth inhibition of cytosolic Salmonella by caspase-1 and caspase-11 precedes host cell death

Sensing bacterial products in the cytosol of mammalian cells by NOD-like receptors leads to the activation of caspase-1 inflammasomes, and the production of the pro-inflammatory cytokines interleukin (IL)-18 and IL-1β. In addition, mouse caspase-11 (represented in humans by its orthologs, caspase-4 and caspase-5) detects cytosolic bacterial LPS directly. Activation of caspase-1 and caspase-11 initiates pyroptotic host cell death that releases potentially harmful bacteria from the nutrient-rich host cell cytosol into the extracellular environment. Here we use single cell analysis and time-lapse microscopy to identify a subpopulation of host cells, in which growth of cytosolic Salmonella Typhimurium is inhibited independently or prior to the onset of cell death. The enzymatic activities of caspase-1 and caspase-11 are required for growth inhibition in different cell types. Our results reveal that these proteases have important functions beyond the direct induction of pyroptosis and proinflammatory cytokine secretion in the control of growth and elimination of cytosolic bacteria

Distinct Quantum States Can Be Compatible with a Single State of Reality

Perhaps the quantum state represents information about reality, and not reality directly. Wave function collapse is then possibly no more mysterious than a Bayesian update of a probability distribution given new data. We consider models for quantum systems with measurement outcomes determined by an underlying physical state of the system but where several quantum states are consistent with a single underlying state---i.e., probability distributions for distinct quantum states overlap. Significantly, we demonstrate by example that additional assumptions are always necessary to rule out such a model.Comment: 5 pages, 2 figure

A Near-Infrared and Thermal Imager for Mapping Titan's Surface Features

Approximately 10% of the solar insolation reaches the surface of Titan through atmospheric spectral windows. We will discuss a filter based imaging system for a future Titan orbiter that will exploit these windows mapping surface features, cloud regions, polar storms. In the near-infrared (NIR), two filters (1.28 micrometer and 1.6 micrometer), strategically positioned between CH1 absorption bands, and InSb linear array pixels will explore the solar reflected radiation. We propose to map the mid, infrared (MIR) region with two filters: 9.76 micrometer and 5.88-to-6.06 micrometers with MCT linear arrays. The first will map MIR thermal emission variations due to surface albedo differences in the atmospheric window between gas phase CH3D and C2H4 opacity sources. The latter spans the crossover spectral region where observed radiation transitions from being dominated by thermal emission to solar reflected light component. The passively cooled linear arrays will be incorporated into the focal plane of a light-weight thin film stretched membrane 10 cm telescope. A rad-hard ASIC together with an FPGA will be used for detector pixel readout and detector linear array selection depending on if the field-of-view (FOV) is looking at the day- or night-side of Titan. The instantaneous FOV corresponds to 3.1, 15.6, and 31.2 mrad for the 1, 5, and 10 micrometer channels, respectively. For a 1500 km orbit, a 5 micrometer channel pixel represents a spatial resolution of 91 m, with a FOV that spans 23 kilometers, and Titan is mapped in a push-broom manner as determined by the orbital path. The system mass and power requirements are estimated to be 6 kg and 5 W, respectively. The package is proposed for a polar orbiter with a lifetime matching two Saturn seasons

Astrophysical factors:Zero energy vs. Most effective energy

Effective astrophysical factors for non-resonant astrophysical nuclear reaction are invariably calculated with respect to a zero energy limit. In the present work that limit is shown to be very disadvantageous compared to the more natural effective energy limit. The latter is used in order to modify the thermonuclear reaction rate formula so that it takes into account both plasma and laboratory screening effects.Comment: 7 RevTex pages. Accepted for publication in Phys.Rev.

Update from the Analysis of High Resolution Propane Spectra and the Interpretation of Titan's Infrared Spectra

Titan has an extremely thick atmosphere dominated by nitrogen, but includes a range of trace species such as hydrocarbons and nitriles. One such hydrocarbon is propane (C3H8). Propane has 21 active IR bands covering broad regions of the mid-infrared. Therefore, its ubiquitous signature may potentially mask weaker signatures of other undetected species with important roles in Titan's chemistry. Cassini's Composite Infrared Spectrometer (CIRS) observations of Titan's atmosphere hint at the presence of such molecules. Unfortunately, C3H8 line atlases for the vibration bands V(sub 8), V(sub 21), V(sub 20), and V(sub 7) (869, 922, 1054, and 1157 per centimeter, respectively) are not currently available for subtracting the C3H8 signal to reveal, or constrain, the signature of underlying chemical species. Using spectra previously obtained by Jennings, D. E., et al. at the McMath-Pierce FTIR at Kitt Peak, AZ, as the source and automated analysis utilities developed for this application, we are compiling an atlas of spectroscopic parameters for propane that characterize the ro-vibrational transitions in the above bands. In this paper, we will discuss our efforts for inspecting and fitting the aforementioned bands, present updated results for spectroscopic parameters including absolute line intensities and transition frequencies in HITRAN and GEISA formats, and show how these optical constants will be used in searching for other trace chemical species in Titan's atmosphere. Our line atlas for the V(sub 21) band contains a total number of 2971 lines. The band integrated strength calculated for the V(sub 21) band is 1.003 per centimeter per (centimeter-atm)

A truthful online mechanism for resource allocation in fog computing

Fog computing is a promising Internet of Things (IoT) paradigm in which data is processed near its source. Here, efficient resource allocation mechanisms are needed to assign limited fog resources to competing IoT tasks. To this end, we consider two challenges: (1) near-optimal resource allocation in a fog computing system; (2) incentivising self-interested fog users to report their tasks truthfully. To address these challenges, we develop a truthful online resource allocation mechanism called flexible online greedy. The key idea is that the mechanism only commits a certain amount of computational resources to a task when it arrives. However, when and where to allocate resources stays flexible until the completion of the task. We compare our mechanism to four benchmarks and show that it outperforms all of them in terms of social welfare by up to 10% and achieves a social welfare of about 90% of the offline optimal upper bound

Managing energy tariffs with agents: a field study of a future smart energy system at home

© 2015 ACM.Interactive autonomous systems are likely to be more involved in future energy systems to assist human users. Given this, we prototyped a future scenario in which householders are assisted in switching electricity tariffs by an agent-based interactive system. The system uses real-time electricity monitoring to instantiate a scenario where participants may have to make, or delegate to their agent (in a variety ways), tariff switching decisions given uncertainty about their own consumption. We carried out a field trial with 12 households for 6 weeks in order to study the notion of autonomy. The results show nuanced ways in which monitoring system performance and taking control is balanced in everyday practice. Our field study provides promising directions for future use of smart systems that help householders manage their energy